Major Contributions
 

1. Reported an entropy-stabilized cation–anion vacancy coupling strategy in high-entropy metal phosphorus trisulfides (MPS₃), enabling semi-quantitative control of coupled metal and sulfur vacancies within a single-phase lattice.

2. Operando Raman and DFT revealed that coupled vacancies promote earlier surface reconstruction with enhanced OH* adsorption while suppressing over-oxidation and metal dissolution, with vacancy-activated Co-centered edge motifs dominating OER kinetics.

3. HE₀.₇PS₃₋δ delivers 212 mV at 10 mA cm⁻², a Tafel slope of 28.6 mV dec⁻¹ and 800 h stability at 200 mA cm⁻²; in an alkaline electrolyzer it operates at 1.8 V at 1 A cm⁻² and runs 300 h at 0.5 A cm⁻².

主要貢獻
 

1. 提出熵穩定的陽離子–陰離子空位耦合策略，於高熵金屬磷三硫化物（MPS₃）單相晶格中半定量調控金屬與硫空位。

2. 臨場拉曼光譜與 DFT 計算顯示，耦合空位促使表面提早重構並增強 OH* 吸附，同時抑制過度氧化與金屬溶出；由空位活化的鈷中心邊緣位點主導析氧反應動力學。

3. HE₀.₇PS₃₋δ 於 10 mA cm⁻² 的過電位為 212 mV、Tafel 斜率 28.6 mV dec⁻¹，並在 200 mA cm⁻² 穩定 800 小時；組成鹼性電解槽後於 1 A cm⁻² 僅需 1.8 V，並在 0.5 A cm⁻² 運轉 300 小時。