Major Contributions
 

1. A Cu-Ni-W tri-component tandem catalyst synthesized via sequential microwave-hydrothermal deposition delivers 97.1% Faradaic efficiency and a record 43.87 mg h⁻¹ cm⁻² ammonia yield from electrochemical nitrate reduction under pulsed electrolysis.

2. Online DEMS and DFT reveal cooperative catalytic roles: Cu facilitates NO₃⁻ adsorption and deoxygenation, Ni promotes water dissociation for *H supply, and W acts as a dynamic *H reservoir to suppress competing hydrogen evolution.

3. Coupling the nitrate reduction anode with glycerol valorization (formic acid production) demonstrates an energy-efficient integrated system, providing a design blueprint for multi-component tandem catalysts for sustainable ammonia electrosynthesis.

主要貢獻
 

1. 以微波水熱法合成的 Cu-Ni-W 三組分串聯催化劑在脈衝電解條件下從電化學硝酸鹽還原實現 97.1% 法拉第效率與創紀錄的 43.87 mg h⁻¹ cm⁻² 氨產率。

2. 線上 DEMS 與 DFT 揭示協同催化作用：Cu 促進 NO₃⁻ 吸附與去氧，Ni 促進水解離提供 *H，W 作為動態 *H 儲庫抑制競爭性析氫。

3. 將硝酸鹽還原陽極與甘油增值（甲酸生產）耦合，展示高效能源整合體系，為多組分串聯催化劑用於永續電合成氨提供設計藍圖。