Explicit illustration of LNbO-NCM811 ∣ LPSCl∣ x-Li (x = b or SnCl) full cell on the interphase evolution and dendrite growth over cycling.

Major Contributions
 

1.Introduced a solvent- and binder-free chlorine-rich artificial protective layer that forms an in-situ LiCl–Sn composite interlayer, effectively suppressing electrolyte decomposition and lithium dendrite growth. 

2.Demonstrated that Sn acts as a nucleation seed, modulating lithium flux through Li–Sn alloy formation and enhancing lithium reversibility, as confirmed by CV and impedance analyses. 

3.Achieved superior electrochemical stability in Li|LPSCl and NMC811|LPSCl|Li full cells, with prolonged cycling performance and high capacity retention at both room and elevated temperatures (30 °C and 55 °C).

主要貢獻

1.無溶劑富氯保護層與原位複合界面：引入了一種無溶劑且無黏結劑（solvent- and binder-free）的富氯人工保護層。該層能透過反應誘導原位形成 LiCl-Sn 複合中間層，有效抑制硫化物電解質的分解以及鋰枝晶（lithium dendrite）的生長。

2.錫 (Sn) 的成核與通量調控機制：透過循環伏安法（CV）與阻抗分析證實，錫（Sn）在界面中充當成核種子（nucleation seed）。它藉由形成鋰錫（Li-Sn）合金來調控鋰離子通量（lithium flux），進而增強鋰金屬沉積/剝離的可逆性。

3.優異的電化學穩定性：該策略在 Li|LPSCl 對稱電池與 NMC811|LPSCl|Li 全電池中均實現了卓越的電化學穩定性。無論是在室溫（30°C）還是高溫（55°C）條件下，電池皆展現了長循環壽命與高容量保持率。