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High-dielectric TiO2-mediated g-C3N4 enhanced self-polarized PVDF hybridized film for highly sensitive wearable triboelectric pressure sensors
高介電常數TiO₂調控g-C₃N₄增強自極化PVDF複合膜於高靈敏可穿戴摩擦電壓力感測器之應用


Yen-Shuo Chiu, Mia Rinawati, Ling-Yu Chang, Sofiannisa Aulia, Ping-Chen Shi, Shu-Chih Haw, Wei-Hsiang Huang*, Ni Luh Wulan Septiani, Brian Yuliarto, Min-Hsin Yeh*
https://doi.org/10.1016/j.cej.2025.161807
SEED Member: Wei-Song Hung, Min-Hsin Yeh

 

Schematic illustration.

 

Major Contributions

1.Developed a novel PVDF-based composite film by integrating TiO₂-modified g-C₃N₄ (TiO₂-CN), forming a uniform and interconnected heterostructure that significantly enhances dielectric properties and prevents particle aggregation. This structure improves the effective contact area, leading to superior triboelectric output compared to conventional PVDF-based materials.

2.Demonstrated that optimizing the TiO₂-to-g-C₃N₄ ratio within the composite maximizes self-polarization and triboelectric performance, resulting in a threefold increase in pressure sensitivity (1.79 V·kPa⁻¹) and a substantial boost in output voltage (up to 136 V), enabling the device to power 94 LEDs in series.

3.Showcased the composite’s multifunctionality for next-generation wearable electronics by achieving high sensitivity, flexibility, and durability in self-powered pressure sensing applications, including real-time biomechanical monitoring, with excellent stability under repeated mechanical stress.




主要貢獻

1.創新開發出以TiO₂修飾g-C₃N₄(TiO₂-CN)為填料的PVDF基複合薄膜,形成均勻且互連的異質結構,有效提升材料的介電性並防止顆粒聚集,進而增大有效接觸面積,顯著提升摩擦電輸出,相較於傳統PVDF基材料具有明顯優勢。

2.通過優化複合材料中TiO₂與g-C₃N₄的比例,最大化自極化與摩擦電性能,使壓力感測靈敏度提升三倍(達1.79 V·kPa⁻¹),輸出電壓大幅提升(最高可達136 V),並可直接點亮94顆LED,展現卓越的能量輸出能力。

3.展現此複合材料於次世代可穿戴電子產品的多功能應用,包括高靈敏度、高柔韌性及耐久性,於自供能壓力感測與即時生物力學監測中表現優異,並在反覆機械應力下展現出色的穩定性。