Schematic illustration of the structure of MOF and its advantages

Major Contributions
 

1.Comprehensive Review of MOF Composite Architectures and Fabrication Strategies
This work systematically reviews the nanoarchitectures of metal-organic frameworks (MOFs), highlighting their structural, morphological, and chemical properties relevant to blue energy harvesting and soft electronics. Various synthesis and characterization methods are detailed, and the challenges of fabricating continuous, defect-free MOF membranes are addressed. The review categorizes and compares multiple strategies for integrating MOFs with polymers, colloids, and nanomaterials to form composites with enhanced mechanical robustness, water stability, and functional performance.

2.Critical Analysis of MOF Composite Membranes for Blue Energy Harvesting
The article provides an in-depth analysis of MOF composite membranes in the context of blue energy (osmotic energy) harvesting. It summarizes recent advances in the design and fabrication of MOF-based membranes, such as Type I (pure MOF on substrate), Type II (MOF-polymer hybrids), and Type III (freestanding composite membranes). The influence of membrane structure, charge asymmetry, and experimental parameters on ion selectivity and power density is discussed, offering guidelines for optimizing next-generation membranes to maximize energy conversion efficiency.

3.Exploration of MOF-Based Composites in Soft Electronics and Self-Healing Materials
The review explores the application of MOF-based composites in soft electronics, including wearable devices and flexible capacitors. It examines how the integration of MOFs with soft polymers imparts enhanced mechanical flexibility, electrical properties, and self-healing capabilities, thus extending device lifetimes and broadening application potential. The article also discusses various composite fabrication techniques—such as in-situ polymerization, grafting, and biomimetic mineralization—demonstrating how these approaches enable the development of advanced, multifunctional materials for next-generation soft electronic devices.

主要貢獻
 

1.MOF複合材料結構與製備策略之系統性回顧
本論文系統性回顧了金屬有機骨架（MOF）之奈米結構設計，著重於其結構、形貌與化學特性，並針對藍色能源收集與軟性電子應用進行深入探討。文中詳述多種MOF的合成與表徵方法，並解析連續且無缺陷MOF膜製備的挑戰。論文亦分類比較多種MOF與高分子、膠體及奈米材料的複合策略，說明如何藉由這些方法提升材料的機械強度、耐水性及功能表現。

2.MOF複合膜於藍色能源收集的關鍵分析
本研究深入分析MOF複合膜於藍色能源（滲透能）收集的應用，總結近年來於膜結構設計與製備上的進展，涵蓋第一型（純MOF於基材）、第二型（MOF-高分子混摻）、第三型（自支撐複合膜）等不同結構。文中探討膜結構、電荷不對稱性與實驗條件對離子選擇性及功率密度的影響，並提出優化次世代膜材料以提升能量轉換效率的設計指引。

3.MOF基複合材料於軟性電子與自癒合材料之應用探討
本論文探討MOF基複合材料於軟性電子領域的應用，包括穿戴式裝置與柔性電容器。文中說明MOF與軟性高分子結合後，如何賦予材料更佳的機械柔韌性、電性與自癒合能力，進而延長裝置壽命並拓展應用潛力。此外，論文詳述多種複合製備技術，如原位聚合、接枝與仿生礦化等，展現這些方法如何促進新一代多功能軟性電子材料的發展。