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Piezocatalytic property of PVDF/Graphene self-assembling piezoelectric membrane for environmental remediation
聚偏氟乙烯/石墨烯自組裝壓電膜在環境修復中的壓電催化特性


T.H. Huang, F.K.C. Espino, X.Y. Tian, J. Widakdo, H.F.M. Austria, O. Setiawan, W.S. Hung*, K.R.S. Pamintuan*, R.B. Leron, C.Y. Chang, A.R. Caparanga, K.R. Lee, J.Y. Lai
Chemical Engineering Journal; 2024
https://doi.org/10.1016/j.cej.2024.150569
SEED Member: W.S. Hung

 
 

Major Contributions

1. Successfully developed a novel self-assembled PVDF/Graphene piezoelectric membrane that achieved significant dye degradation efficiency: 80.2% for methylene blue, 85.6% for crystal violet, 73.8% for methyl orange, and 96.1% for rhodamine B within 2 hours.

2. Demonstrated that graphene addition induced PVDF crystalline phase transformation from α-phase to electroactive β-phase through self-assembly, increasing the electroactive phase ratio from 34.58% to 95.85%, which significantly enhanced the membrane's piezoelectric properties.

3. Established that the optimized membrane exhibits superior piezoelectric performance with the highest Vpp value of 4.26 V and d33 value of 13.31 pm/V, providing a green strategy for future applications in environmental remediation.


主要貢獻

1. 成功開發新型自組裝PVDF/石墨烯壓電膜,在2小時內實現顯著的染料降解效率:亞甲基藍80.2%、結晶紫85.6%、甲基橙73.8%以及羅丹明B 96.1%。

2. 證實添加石墨烯能誘導PVDF晶相從α相轉變為具電活性的β相,通過自組裝過程使電活性相比例從34.58%提升至95.85%,大幅提升膜的壓電特性。

3. 確立最佳化膜體展現優異的壓電性能,具有最高4.26 V的Vpp值和13.31 pm/V的d33值,為未來環境修復應用提供綠色策略方案。